Abstract
Nuclear magnetic resonance techniques utilizing 195 Pt and 13 C have been employed to study the formation of dihydroxo platinum(IV) compounds in the hydrogen peroxide oxidation of Pt(II) complexes. The trans-dihydroxo isomer is the exclusive kinetic product for oxalato, malonato, and chloro complexes. Isotopic labeling experiments with H 2 18 O demonstrate that one hydroxo ligand originates from hydrogen peroxide, while the trans hydroxo ligand originates from water. Hydrogen peroxide oxidation in methanol or ethanol results in the formation of trans-hydroxomethoxo- and trans-hydroxoethoxoplatinum(IV) complexes.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
