Abstract
Nuclear resonances in transient radicals produced in liquids by pulse radiolysis have been detected by using NMR of their reaction products. The NMR intensities are affected by application of rf corresponding to nuclear resonances of the radical intermediates. NMR-detected nuclear resonance (NMR-NR) spectra for several chemical systems are presented. Information from these spectra about relative populations of the radical magnetic energy levels is explained with the radical pair theory of chemically induced magnetic polarization, both electron (CIDEP) and nuclear (CIDNP). For some systems, weak lines in the NMR-NR spectra have been assigned as due to double quantum transitions between energy levels differing by two in nuclear spin quantum number.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
