Abstract

Abstract Caesium N.M.R. spectra of the caesium ion have been measured in a nematic lyotropic liquid-crystalline solution prepared from caesium decylsulphate/decanol/water. The contributions of an asymmetry parameter, a second order quadrupole coupling and a hexadecapole coupling to the spectra have been discussed. The N.M.R. spectra was shown to be consistent with the occurrence of a hexadecapole interaction in the quadrupole split spectrum. The ratio = 1:0.0000034 was obtained.

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