NOx removal capacity and compressive strength of photocatalytic cementitious materials with various color properties

Abstract

The photocatalytic cementitious materials (PCM) are expected to alleviate air pollution due to the direct utilization of natural solar energy. However, the color properties of cementitious materials have significant effect on the photocatalytic performance of PCM. In the present study, the colorful PCM is prepared using various colorants. The effect of color properties of cementitious materials on the NOx removal capacity of PCM is researched, and the related mechanism is analyzed by optical analysis. Furthermore, the effect of colorants on the compressive strength of PCM is studied. Results showed that the NOx removal capacity of PCM is decreased by the presence of colorants. As the 5% of black, yellow, red, and blue colorants are used, the NOx removal capacity of PCM is reduced by 73%, 48%, 21%, and 19%, respectively. Both the nano-TiO2 and cement in the PCM can absorb UV light. Colorants could enhance the UV light absorption capacity of cement, leading to a decrease in the UV light absorption of nano-TiO2, which is harmful to the generation of electron-hole pairs. Moreover, the Fe-phase in colorants could improve the surface charge separation resistance of nano-TiO2, limiting the efficiently separated electron-hole pairs. Therefore, the photocatalytic performance of PCM is weakened by the presence of colorants. The compressive strength of PCM is decreased by using colorants, but the reduction ratio at 28 d is no more than 10%, with the content of colorants within 5%. This research can guide the color design of PCM in practical applications.