Novolac phenolic resin and graphene aerogel organic-inorganic nanohybrids: High carbon yields by resin modification and its incorporation into aerogel network

Abstract

Graphene oxide (GO) modified with furfuryl alcohol and (3-aminopropyl) triethoxysilane (GOFASi) was used in two separate ways for preparation of novolac resin nanohybrids. In the first procedure, graphene-containing silica aerogel (GA) was obtained by incorporation of GOFASi into silica aerogel network using tetraethyl orthosilicate (TEOS). Then, GA was used as an additive in novolac resin matrix. In the second procedure, the synthesis of a hybrid novolac resin was accomplished by network formation via the reaction of GOFASi with (3-glycidyloxypropyl)trimethoxysilane-modified novolac resin and TEOS. The thermal stability and the carbon yield of the hybrid resins obtained by the two procedures were compared. Fourier transforms infrared spectroscopy, X-ray photoelectron spectroscopy, and thermogravimetric analysis showed that both GO and the novolac resin were successfully modified. Aerogel formation was proved by Raman, X-ray diffraction, N2 adsorption and desorption isotherms, and by scanning and transmission electron microscopies.