Novel Zn-Fe engineered kiwi branch biochar for the removal of Pb(II) from aqueous solution

Abstract

In this study, a novel adsorbent made from kiwi branch biochar modified with Zn-Fe (KB/Zn-Fe) was compared with original biochar to the Pb(II)'s adsorptivity from waste water. The adsorbent was synthetized by liquid-phase deposition. Batches of sorption tests were performed, and the biochars' representative properties were tested. Characterizations revealed the physicochemical properties of biochars and showed that the KB/Zn-Fe composites were successfully synthesized. The Langmuir model and pseudo-second-order kinetic model were proven to satisfactorily fit the original biochar and KB/Zn-Fe. The KB/Zn-Fe showed Langmuir maximum adsorption ability to Pb (II) in aqueous solution of 161.29 mg g-1, compared with 36.76 mg g-1 for original biochar. The adsorption ability of Pb(II) decreased and the Pb(II) removal efficiency increased with increasing biochar dose. The effect of co-existence of NO3- to the absorptive capacity of KB/Zn-Fe on Pb(II) was unremarkable, but Cl- could increase the absorptive capacity. Multiple Pb(II) adsorption mechanisms by KB/Zn-Fe include surface precipitation of metal hydroxides, complexation with active functional groups and ion-exchange. This work provides guidance for future production of biochar with efficient adsorption ability, which could be used to remove Pb(II) ions from wastewater.