Novel synthesis organic–inorganic heterojunctions of protonated g-C3N4/Fe3O4/AgBr/AgCl/AgI quinary magnetic photocatalyst with enhanced visible-light photocatalytic degradation of methylene blue in water

Abstract

A novel magnetic quinary nanocomposite, protonated g-C3N4/Fe3O4/AgBr/AgCl/AgI, was synthesized using a wet chemical method. The multi-heterojunction photocatalyst with multi-carrier source and multi-channel carrier transport is constructed to enhance the photocatalytic degradation performance of pure g-C3N4. The design of the quinary nanocomposite is also an effective approach to solve the chemical stability problem of silver halides. The photocatalytic degradation efficiency under visible light irradiation was analyzed for methylene blue (MB) as the target organic pollutant. The quinary nanocomposite with 10 % g-C3N4 displayed high photocatalytic performance, with 83 % of MB degraded under 6 h LED white light irradiation. The effective quinary nanocomposite has good magnetic properties and can be magnetically separated to prevent secondary pollution of the photocatalyst in water. Parameters such as initial concentration of pollutant, initial solution pH, and light source were studied. Zeta potential results showed that the quinary nanocomposite could disperse homogenously to decrease aggregation in the solution. The photocatalytic degradation mechanism was investigated, and the mineralization results were analyzed based on liquid chromatography-mass spectroscopy (LC-MS) and total organic carbon (TOC). It was found that the hydroxyl and superoxide radicals were major reactive species by scavenging experiments. Additionally, protonated g-C3N4/Fe3O4/AgBr/AgCl/AgI nanocomposite showed excellent reusability after magnetic separation and regeneration, thus suggesting it to be a promising photocatalyst for treating wastewater containing organic contaminants.