Abstract

Rh(I)-catalyzed cycloisomerization of 1,3-dienes with alkenes in a tether proceeded smoothly, giving cyclopentene derivatives in good yields. It was interesting that the existence of a heteroatom between a 1,3-diene moiety and alkene in the tether affected the reaction course and that only a [4 + 2] cycloaddition product was produced.

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