Novel procedure to determine the stress-strain relation of Lithium-ion Batteries through indentation test

Abstract

This study proposes a novel approach to convert the load–depth curve measured in the experimental indentation test into stress–strain curves. Due to the lack of the tensile test results for the cylindrical lithium-ion battery (LIB) cell, a combination of the analytical analysis and the inverse optimization approach is first conducted as a reference point to determine the elastoplastic constitutive equation, which can predict the response of cylindrical LIB cell cells under the cylindrical indenter. The obtained load-depth curves from the robust optimization algorithm are in good agreement with the experimental loading–unloading curves. This novel approach includes a new definition of the contact area between the cylindrical indenter and the cylindrical LIB cell. Finite element models validate the measured contact area values from the analytical approach. The analytical approach in this study can accurately capture the stress–strain curve validated with optimization results. Afterward, different single indentation tests are conducted to estimate the reduction of Young’s modulus through the increasing indentation depth. Noteworthy, a definition of the indentation strain can physically interpret the indentation strain in the case of two crossed cylinders. The cell voltage is measured during the indentation test to detect the internal short circuit in the LIB cell. In homogenized modeling, the damage of the LIB cell is considered, which is an essential indicator of the internal short circuit of a LIB cell and possible thermal runaway.