Abstract
Metal–organic gels (MOGs) are attracting increasing attention for removal of organic dyes from aqueous solution and for catalysis of Si–H insertion reactions. Herein, we report that a reaction of porphyrin derivative 1 with Rh2(OAc)4 generates stable metal–organic gels and subsequent subcritical carbon dioxide drying affords metal–organic aerogels. Owing to their micro- and mesoporosity, the aerogels adsorbed dyes. Moreover, aerogel I catalyzed Si–H insertion reactions to give organosilicon compounds in high yields.
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