Abstract
A new type of linking of α-olefins upon polymerization has been achieved by catalysis with nickel(0) complexes and [X2NP(NX)2], X = Me3Si. 2,ω-linking leads to polymers with methyl branches at well-defined intervals; products of type 1 are obtained from linear α-olefins.
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Schedule a callMore From: Angewandte Chemie International Edition in English
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