Novel polycarbonate membrane embedded with multi-walled carbon nanotube for water treatment: a comparative study between bovine serum albumin and humic acid removal

Abstract

Flat sheet polycarbonate/multi-walled carbon nanotube (PC/MWCNT) nanocomposite membranes with different nanoparticle contents were prepared by applying the phase inversion method. The characteristics of the prepared membranes were analyzed by field emission scanning electron microscopy (FE-SEM), atomic force microscopy (AFM), water contact angle, porosity, pure water flux (PWF), and mechanical properties. The performance of the membranes was evaluated in a submerged membrane system for two cycles and also for the filtration of humic acid (HA) and bovine serum albumin (BSA). The obtained results revealed that nanocomposites containing 0.1 wt% of MWCNTs showed better hydrophilicity, porosity, PWF, and mechanical properties. The FE-SEM images from surface indicated that the density and pore size of membrane increased from 0 to 0.1 wt% of MWCNTs. Moreover, according to AFM images, the PC/MWCNT-0.1 membrane showed a smoother surface than other samples. The antifouling performance of the membranes in a submerged membrane system revealed that the BSA solution flux for all membranes was lower than that of the HA solution due to the pore blocking of membranes occurring in the initial filtration of BSA. Apart from that addition of the 0.1 wt% of MWCNTs led to significant improvement in the fouling recovery ratio in the filtration of both HA and BSA because of the lower roughness and high hydrophilicity of the membrane surface. The rejection results revealed that the neat PC membrane had the highest value in the removal of HA and BSA with respect to other samples due to the formation of a thicker and denser cake layer on the membrane surface.