Novel polyamide/silica/chitosan covalent hybrid: One-step BIC/sol-gel preparation at room temperature and dual applications in Hg2+ electrochemical probing and dye adsorption

Abstract

Room-temperature preparation of polymer-based covalent hybrids, which with multiple functional characteristics, is instrumental to overcome the performance shortcomings of single-polymer materials and broaden their applications thus. Herein, by introducing chitosan (CS) as a starting substrate into benzoxazine-isocyanide chemistry (BIC)/sol-gel reaction system, a novel polyamide (PA)/SiO2/CS covalent hybrid (PA-Si-CS) was successfully prepared in-situ at 30 °C. PA-Si-CS's chemical structure and elementary properties were characterized here. The introduction of CS combining with the presence of diverse N, O-containing segments (amide, phenol -OH, Si-OH, etc.) in PA-Si-CS provided its synergistic adsorption for Hg2+ and anionic dye Congo red (CR). The capture of PA-Si-CS for Hg2+ was rationally applied to the “enrichment”-type electrochemical probing of Hg2+. Relevant detection range, detection limit, interference, and probing mechanism were systematically analyzed. Compared with the experimental results of control electrodes, the electrode modified with PA-Si-CS (PA-Si-CS/GCE) showed a significantly enhanced electrochemical response to Hg2+, with a detection limit up to ~2.2 × 10−8 mol/L. In addition, PA-Si-CS also exhibited the specific adsorption for CR. Systematic analyses of dye adsorption selectivity, kinetics, isothermal models, thermodynamics, and adsorption mechanism told that PA-Si-CS can be used as an efficient CR adsorbent, with a maximum adsorption capacity of ~348 mg/g.