Abstract
A novel oxygen sensor using hot spot on ceramic rod of high-T c superconductor RBa2Cu3O7−δ (R: rare earth element) has been developed. The hot spot appears by the self-heating of the local part on the RBa2Cu3O7−δ ceramic rod when a voltage above threshold is applied at room temperature. This sensor operates without any separate heater by taking advantage of the high temperature of the hot spot wherein oxide ions can diffuse easily. The oxygen concentration is determined from the value of the current flowing through the rod by utilizing the change in the resistivity of the hot spot depending on oxygen partial pressure in atmosphere. Oxygen concentration of 0∼100% can be detected with high sensitivity and the response time is several seconds. The response performance of this oxygen sensor is almost the same as that of limiting-current-type zirconia sensor operating at 500°C.
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