Abstract
2-Nitrodiene 1 reacted with 3-mercapto-1,2,4-triazole and cyclohexyl thiol to yield compounds 3 and 4 , respectively. Compounds 7a – d were obtained by reactions of 6a – d with 2 . The novel N,S-substituted dienes 9a – c were obtained by treatment of compound 6b with the piperazine derivatives 8a–c . Compound 6b was reacted with 10 to give compound 11 as a new morpholine derivative. Compound 6b gave a new monobutadienyl homopiperazine 13 when reacted with homopiperazine in methylene chloride. Compound 4 was structurally characterized by single-crystal X-ray diffraction.
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