Abstract
A trigonal bipyramid made up of sulfur atoms with two cobalt atoms in the cavity, or two face-sharing CoS4 tetrahedral—both are apt descriptions of the structure of the title anion 1. The CoCo distance is remarkably short (2.491(1) Å), and the isopropyl groups of the three bridging thiolato ligands have a paddle-wheel-type arrangement about a C3 axis. Complex 1 is obtained from cobalt(II) nitrate and sodium propane-2-thiolate and can be isolated as the ammonium salt.
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