Abstract

The novel Zn(II) based complex, [Zn(pz25dc)(DMF)2] (1) (where pz25dc stands for pyrazine-2,5-dicarboxylate ligands) has been synthesized by the direct mixing method. This structure confirmed by a combination of physic-chemical methods features a 1-D linear polymeric chain. The local structure of a Zn atom in the unit cell of [Zn(pz25dc)(DMF)2] derived from EXAFS data is in a good agreement with that revealed from PXRD data.

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