Novel Magnetically Driven Superhydrophobic Sponges Coated with Asphaltene/Kaolin Nanoparticles for Effective Oil Spill Cleanup.

Abstract

Fast and effective cleanup of oil spills remains a global challenge. A modified commercial sponge with superhydrophobicity, strong absorption capacity, outstanding magnetic response, and fire resistance were fabricated by a facile and inexpensive route of dip-coated melamine sponge carbonization. The low-cost petroleum asphaltene and kaolin nanoparticles were used as the dip-coating reagent. High absorption capacity of the fabricated sponges allowed rapid and continuous removal of oil contaminants. Taking advantage of the good refractory property, the sponges can be used in burning conditions and directly reused after burning out of the absorbed oil. Reusability tests showed that the modified sponges still maintained high absorption capacity (>85%) after six regeneration and reuse cycles. These characteristics make the fabricated sponge a promising aid to promote effective in situ burning cleanup of oil spills, contributing as a magnetic oil collector and a fire-resistant flexible boom. An example usage scenario of the sponges applied to in situ burning cleanup of oil spills is described.