Novel light-weight, high-performance anode-supported microtubular solid oxide fuel cells with an active anode functional layer

Abstract

Influence of the air-gap, the distance from the tube-in-orifice spinneret to the upper surface of the external coagulant bath during the extrusion/phase-inversion process, on the microstructure of nickel – yttria-stabilized zirconia (Ni–YSZ) hollow fibers has been systematically studied. When the air-gap is 0 cm, the obtained Ni–YSZ hollow fiber has a sandwich microstructure. However, when the air-gap is increased to 15 cm, a bi-layer Ni–YSZ hollow fiber consisting of a thin layer with small pores and a thick support with highly porous fingerlike macrovoids has been achieved. The output power density of microtubular solid oxide fuel cells (MT-SOFCs) with a cell configuration of Ni–YSZ/YSZ/YSZ–LSM increases from 594 mW cm−2 for the cells with the Ni–YSZ anode of sandwich microstructure to 832 mW cm−2 for the cells with the Ni–YSZ anode of bi-layer microstructure at 750 °C, implying that to achieve the same output power density, the weight of the cells with the bi-layer anode support can be reduced to 41.5% compared with that of the cells with the sandwich anode support. Thermal-cycling test shows no obvious degradation on the open-circuit-voltage (OCV), indicating that the MT-SOFCs have robust resistance to thermal cycling.