Novel heterogeneous Fenton catalysts for promoting carbon iron electron transfer by one-step hydrothermal synthesization

Abstract

Carbon materials play a crucial role in promoting the Fe(III)/Fe(II) redox cycle in heterogeneous Fenton reactions. However, the electron transfer efficiency between carbon and iron is typically low. In this study, we prepared a novel heterogeneous Fenton catalyst, humboldtine/hydrothermal carbon (Hum/HTC), using a one-step hydrothermal method and achieved about 100 % reduction in Fe(III) during synthesis. Moreover, the HTC continuously provided electrons to promote Fe(II) regeneration during the Fenton reaction. Electron paramagnetic resonance (EPR) and quenching experiments showed that Hum/HTC completely oxidized As(III) to As(V) via free radical and non-free radical pathways. Attenuated total reflectance Fourier-transform infrared (ATR-FTIR) and two-dimensional correlation spectroscopy (2D-COS) analyses revealed that monodentate mononuclear (MM) and bidentate binuclear (BB) structures were the dominant bonding methods for As(V) immobilization. 40 %Hum/HTC exhibited a maximum As(III) adsorption capacity of 167 mg/g, which was higher than that of most reported adsorbents. This study provides a novel strategy for the efficient reduction of Fe(III) during catalyst synthesis and demonstrates that HTC can continuously accelerate Fe(II) regeneration in heterogeneous Fenton reactions.