Abstract

C,O-Chelated tetracarbonyl[o-methoxyphenyl(methoxy)- carbene] complexes of molybdenum(0) and tungsten(0) react with tin tetrahalides SnX4 (X = Cl, Br, I) by oxidative decarbonylation and incorporation of two halides to form novel chelated hepta-coordinated Fischer-type tricarbonyl- (bishalogeno)carbene molybdenum(II) and tungsten(II) complexes

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