Novel gC3N4/MgZnAl-MMO derived from LDH for solar-based photocatalytic ammonia production using atmospheric nitrogen.

Abstract

The development of catalysis technologies for sustainable environmental applications, especially an alternative to ammonia (NH3) production under the Haber-Bosch process, has gained a lot of scope in recent days. The current work demonstrated a green synthesis of graphitic carbon nitride (gC3N4) containing magnesium-zinc-aluminium mixed metal oxides (MgZnAl-MMO) derived from layered double hydroxide (LDH) for visible light aided catalytic production of ammonia. Pyrolysis-hydrothermal techniques were adopted for the synthesis and fabrication of the gC3N4/MgZnAl-MMO catalytic composite. Characterization results of field emission scanning electron microscope (FESEM), X-ray diffraction (XRD), UV-visible spectroscopy, photoluminescence (PL), etc. showed the desired properties and functionalities like semi-crystalline structure with rough surface morphology that enhance the sorption reactions. Catalytic composite gC3N4/MgZnAl-MMO showed a bandgap energy of 2.16eV that is considerably shifted toward the visible range when compared to gC3N4 (2.39eV) and MgZnAl-MMO (2.93eV). The results were also well complied with XPS results obtained that promote solar-based photocatalysis. The gC3N4/MgZnAl-MMO assisted photocatalytic production of NH3 in an aqueous media proved to be acceptable by the production of a maximum 47.56μmol/L NH3 under visible spectrum employing a light emitting diode (LED) source. The results showed that the advancement of catalyst for desired functionalities and NH3 production using LED simulating solar light-aided catalysis would be an alternative to the Haber-Bosch process and solar-based sustainable processes for NH3 production.