Abstract
Radical polyaddition of bis(α-trifluoromethyl-β,β-difluorovinyl) terephthalate [CF 2C(CF 3)OCOC 6H 4COOC(CF 3)CF 2] (BFP) with 18-crown-6 to produce fluorinated polymer bearing crown ether moiety in main chain is described. Prior to polyaddition, the model reaction of 2-benzoxypentafluoropropene [CF 2C(CF 3)OCOC 6H 5] (BPFP) with 18-crown-6 was investigated to afford suitable reactions condition for polyaddition. The polyaddition of BFP with 18-crown-6 yielded a soluble polymer bearing M n=5.5×10 4 with unimodal molecular weight distribution after purification by reprecipitation with cold ethanol.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Paper version not known
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
