Abstract
The article highlights the fabrication of a novel CuBi2O4-BiOCl/rGO heterojunction nanocomposite as a renewable visible light photocatalyst for the quick disintegration of a persistent fluoroquinolone-based antimicrobial drug, i.e., enrofloxacin (ENF) in aquatics. CuBi2O4-BiOCl (CBO-BOC) nanocomposites (NCs) of varying BOC stoichiometric ratios were synthesized, of which CBO-(30%) BOC NC (CB-30) revealed top photocatalytic traits, which was analogously dispersed onto reduced graphene oxide (rGO) nanosheets, to serve as the visible light photon responsive materials. The electron microscopic and spectroscopic techniques were deployed to understand the CB-30/rGO heterostructure's surface topography and structural morphology. The FE-SEM, HR-TEM and XPS analysis confirmed the dispersion of CBO nanospheres onto the BOC nanoflakes and further confirmed the successful imbuement of CB-30 NCs onto the rGO nanosheets. The CB-30/rGO photocatalyst revealed excellent porosity and surface area for the fast dissipation of pharmaceutical pollutants. The impact of various operating parameters, such as solution pH, drug concentration, CBO-BOC stoichiometry, CB-30/rGO dosage, photosensitizers/electron acceptors, light intensity and matrix tolerance limits, were augmented to enhance the photocatalytic efficiency of the proposed new-age photocatalyst. Under optimized conditions, complete drug mineralization was achieved in ≤0.33 h for complete mineralization of 30 ppm of ENF, using 0.075 g of photocatalyst. The time-dependent profiling of photoproducts/intermediates derived from the photocatalytic degradation of ENF was monitored by HR-MS analysis. The acute and chronic toxicity effects of ENF and its organic intermediate were predicted using the ECOSAR model for selected aquatic life forms. The photocatalyst exhibited reusability up to seven cycles, with excellent thermal/chemical stability, for pollutant decontamination from industrial effluents and environmental samples.
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