NOVEL COMBINATION OF TRISODIUM CITRATE AND TRISODIUM PHOSPHATE IN REACTIVE DYEING OF COTTON: AN ATTEMPT TO REDUCE ENVIRONMENTAL IMPACT

Abstract

"Reactive dyes are most widely used for dyeing cellulosic fabrics due to their excellent wet fastness properties, the brilliancy of shades and a wide gamut of colours. However, the exhaustion of reactive dye requires a large quantity of inorganic electrolyte, which results in excessive total dissolved solids (TDS) values of the resultant effluent. Such high TDS-containing effluents are challenging to treat and require advanced treatment techniques. The discharge of high-TDS containing effluent into water-bodies can increase the salinity of the aquatic system, which can affect the delicate biochemistry of the aquatic life. This necessitates the exploration of alternative chemicals for reducing the TDS of the effluents in reactive dyeing. The current study explores the alternate combination of trisodium citrate (TSC) and trisodium phosphate (TSP) as an eco-friendly replacement of inorganic salts and alkali in the dyeing of cotton by the exhaust process. The TSC-TSP combination resulted in an insignificant variation in exhaustion, fixation and fastness ratings compared to the conventional salt-soda combination. The colour values showed marginal variations in the individual cases of dyes. However, the use of the TSC-TSP combination showed a great promise in reducing the TDS of the effluent (by 66%), which is a major concern in effluent treatment. TSC being organic, some increase in COD/BOD values was obtained; however, the effluent remained in a category of easily treatable ones. "