Abstract
AbstractMass spectral peaks of cluster ions believed to be due to penta‐μ‐acetato‐μ4‐oxo‐tetramagnesium and tri‐μ‐acetato‐μ3‐oxo‐trimagnesium, or the corresponding zinc compounds, were detected when magnesium acetate or zinc acetate was heated on a tungsten filament and impacted at the same time by an electron beam. Structures of these non‐transition metal complexes are analogues of the so‐called ‘electron‐sponge’ complexes, [Ru3O(OAc)6L3]. Previously reported new cluster ions from lithium acetate are formulated by similar structures.
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