Novel chitosan/citric acid modified pistachio shell/halloysite nanotubes cross-linked by glutaraldehyde biocomposite beads applied to methylene blue removal

Abstract

In this study, Cht/PS-CA/HNT biocomposite adsorbent was synthesized using halloysite nanotube as nanomaterial, chitosan which is a biodegradable and biocompatible biopolymer, pistachio shell as biomass source, citric acid as biomass modifier. The removal of methylene blue dyestuff on the synthesized new Cht/PS-CA/HNT from the aqueous medium by adsorption method was investigated. Experimental parameters such as dye concentration, contact time, amount of adsorbent, solution pH and temperature, which affect the adsorption process, were investigated. The adsorption experimental data were analyzed with the Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherms, which are widely used in aqueous solutions, and it was decided that Langmuir is the most suitable isotherm. The maximum adsorption capacity of the monolayer was calculated to be 111.14 mg/g. Optimum contact time and adsorbent dose were determined as 90 min and 1 g/L. Adsorption experimental data were applied for Pseudo-first-order and Pseudo-second-order kinetic models and it was decided that the most suitable kinetic model was pseudo-second-order. Thermodynamic evaluation of adsorption showed that adsorption is endothermic and adsorption is spontaneous.