Abstract

Novel chiral tetraaza ligands, N 1, N 2-bis(2-(piperidin-1-yl)benzylidene)cyclohexane-1,2-diamine 1 and N 1, N 2-bis(2-(piperidin-1-yl)benzyl)cyclohexane-1,2-diamine 2, have been synthesized and fully characterized by analytical and spectroscopic methods. The structure of ( R, R)- 1 has been established by X-ray crystallography. Asymmetric transfer hydrogenation of aromatic ketones with the catalysts prepared in situ from [IrHCl 2(COD)] 2 and the chiral tetraaza ligands in 2-propanol gave the corresponding optically active secondary alcohols in high conversions and good ees (up to 91%) under mild reaction conditions.

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