Abstract

AbstractSome examples of novel chemistry of lactones polymerization are presented. New evidences on β‐lactones polymerization by akali metal alkoxides and, also unusual in organic chemistry, C‐C bond scission in β‐lactones polymerization induced by alkali metal supramolecular complexes are discussed. Preparation of functional polyesters and various block polymers exhibiting “tailored” properties are also described.

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