Abstract
Abstract A novel carbinolamine complex, [Co(N-(3,7-diaza-9-aminononyl)-α-amino-α-hydroxymalonato)]+, was obtained from the reaction of ketomalonic acid and trans-[CoCl2(2,3,2-tet)]+ and the molecular structure was determined by X-ray analysis. A free OH group in the carbinolamine linkage had aromatic properties despie it binds to an sp3 carbon.
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