Abstract

A novel bis-naphthalimidocalix[4]arene-Cu(II) supramolecular complex has been observed to provide an efficient recognition system for CN− ions in aqueous medium. The binding stoichiometry of bis-naphthalimidocalix[4]arene and copper ion has been found to be 1:1 while that for bis-naphthalimidocalix[4]arene-Cu(II) and cyanide ion it has been determined to be 1:2.

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