Abstract
The title clathrate Cd(dl-pn)Cd(CN)4·CH2CICH2CI (pn=dl-1,2-diaminopropane=dl-propy-lenediamine) crystallizes in the monoclinic space groupP2 ,a = 8.278(2),b = 14.904(2),c = 14.477(1) A,β = 91.24(1)°,V = 1785.7(1) A3,Z = 4,R = 0.068 for 4993 independent reflections. A novel three-dimensional host is built of the alternate array of the pn-chelated octahedral Cd and the tetrahedral Cd(CN)4 linked at every N atom to the former Cd to provide a cage-like cavity for a pair of 1,2-dichloroethane guest molecules.
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More From: Journal of Inclusion Phenomena and Molecular Recognition in Chemistry
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