Abstract

Oxidation of Quincorine (QCI) and Quincoridine (QCD) has been investigated, giving bicyclic α-amino acids and dicarboxylic acid derivatives, which are epimerically and also enantiomerically pure. Acidic Cr(VI)-mediated oxidation (Jones oxidation) has been optimized with respect to reaction conduct and work up (addition of ethylenediamine).

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