Abstract
A simple and efficient approach for the preparation of hydroxylammonium nitrate from the hydrolysis reaction of cyclohexanone oxime in the presence of nitric acid has been developed in this work. The effects of the molar ratio of cyclohexanone oxime to nitric acid, the amount of water, the reaction temperature, the reaction time, and the extraction solvent on the hydrolysis reaction were investigated. The results indicated that the conversion of cyclohexanone oxime can reach 62.6% with 96.9% selectivity to hydroxylammonium nitrate and 97.4% selectivity to cyclohexanone under the optimal reaction conditions. In addition, the possible acid-catalyzed hydrolysis reaction mechanism is discussed. This work might be very significant for establishing such a preparation method for hydroxylammonium salts from the hydrolysis reaction of oxime in the chemistry and chemical engineering fields.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
