Novel alkali intercalated and acid-exfoliated biochars with enhanced surface areas for contaminant adsorption applications

Abstract

Cost-effective and eco-friendly adsorbents are essential in environmental engineering and biochar is a promising material from the perspective. A novel and efficient surface modification approach involving alkali intercalation and acid exfoliation was designed in this study to enhance the physicochemical properties of biochar. The alkali intercalation process utilizes potassium hydroxide (KOH), while acid exfoliation involves varying HNO3, H2SO4, and H3PO4 concentrations. A simple two-stage pyrolysis process was employed to facilitate the intercalation-exfoliation modification. The modified biochars were characterized using BET, SEM, XRD, etc., to understand physicochemical properties. To quantify the effectiveness of the modifications, adsorption of malachite green dye as a model moiety was investigated. Dye removal sorption rates exceeding 99 % were recorded in the case of the biochars modified through a two-step process using KOH and 0.1MH3PO4. Specifically, the highest contaminant removal of 99.9 % was recorded when 60 mg of the KOH-0.1MH3PO4 biochar was employed, which is significantly higher than unmodified biochar’s 45.41 % removal at a higher dosage of 100 mg. Moreover, the adsorption kinetics revealed that all the modified biochars attained the maximum removal concentrations (∼99 % removal) in a mere 300 min, indicating a tenfold improvement in adsorption rate from unmodified biochar's requirement of over 5000 min. The results achieved through this study provide a cost-effective, fast, and environment-friendly technology for enhancing the adsorption characteristics and performance of biochars toward contaminant removal.