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Abstract
Two mononuclear Ag(I) complexes, [Ag(tbsb)](NO 3)·DMF ( 1) and [Ag(tbsb)](NO 3)·4.5H 2O ( 2) {tbsb=1,3,5-tris(2-benzimidazol)sulfanylmethyl)-2,4,6-trimethylbenzene}, have been synthesized by self-assembly reaction of AgNO 3 with tbsb and characterized structurally. The silver atoms of both the complexes are coordinated by the imine nitrogen atoms from a tripodal ligand (tbsb) to form two- and three-coordinate structures, respectively. Complex 1 presents the first example of silver (I) compound of the tripodal ligand possessing propeller-like structure.
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