Abstract

Ho3+ and Nd3+/Ho3+ doped fluoroaluminate glass samples were fabricated by the melt-quenching method and showed high transmittance and a wide transparency window. Under 808 nm pumping, emission at 3.9 µm, corresponding to the Ho: 5I5→5I6 transition, was observed. The presence of Nd3+ strongly enhances the Ho3+ emission. The emission and absorption cross-sections were calculated using the Judd-Ofelt, Füchtbauer-Ladenburg and McCumber theories and the energy transfer mechanism between Nd3+ and Ho3+ was analyzed. The most efficient 3.9 µm emission was obtained when the concentration ratio of Nd3+: Ho3+ is 1: 2.

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