North-south geographic heterogeneity and control strategies for polycyclic aromatic hydrocarbons (PAHs) in Chinese lake sediments illustrated by forward and backward source apportionments

Abstract

As universal and supervirulent pollutants, understanding the potential sources of polycyclic aromatic hydrocarbons (PAHs) in lakes is critical for formulating pollutant control policies that will ensure the ecological safety of aquatic environments. Geographic heterogeneity of PAHs in lake sediments from China nationwide was investigated to indicate north-south dissimilarities in PAH levels and sources and propose specific PAH control strategies. Geographic PAH patterns showed that higher concentrations were found in the south compared to the north due to higher energy consumption and more intense industrial activities. Furthermore, the primary contributors in the south were high molecular weight (HMW) PAHs, whereas low molecular weight (LMW) PAHs were dominant in the north. The results of forward source apportionment based on the PAH emission method (EM) were consistent with the backward method using the positive matrix factorization (PMF) model, which verified the feasibility of the combined methods. Petroleum from transport was the dominant PAH source in the south, and purifying gasoline and diesel, promoting new energy vehicles and direct injection engines might effectively reduce PAH emission. Domestic coal was the main PAH source in the north, thereby adding active substance in coal and using cleaner energy could reduce PAH release.