Abstract
A rigorous normal coordinate analysis is made for the molecules CF 3H and CF 3D using all the available vibrational data: 12 frequencies, 4 Coriolis coupling constants and 3 centrifugal stretching constants. 2 types of force fields have been obtained: a General Harmonic Force Field with 12 parameters and a modified Urey-Bradley Force Field with 9 parameters. Both the force fields account for the observed data reasonably well.
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