Abstract
The chromatographic behavior of five macrocyclic antibiotics (erythromycin, troleandomycin, tylosin, rifamycin B, and rifampicin) has been compared on normal and reversed-phase TLC plates. Mobile phases were wide-ranging mixtures containing from 0 to 100%, ( v/v ), esters or ketones in dimethyl sulfoxide (DMSO) or hexamethyldisiloxane (HMDSO). Chromatographic retention data and a possible retention mechanism are discussed.
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