Nonradiative triplet-singlet transfer of electronic excitation energy between dye molecules in the vicinity of the silver-film surface

Abstract

Nonradiative triplet-singlet transfer of electronic-excitation energy between molecules of organic dyes (erythrosine and methylene blue) in a polymer film that is deposited on the surface of a silver layer is experimentally studied. It is demonstrated that the energy-transfer efficiency in such a system is lower than the efficiency in the samples without metal layers. The results of the proposed mathematical model are in qualitative agreement with the experimental data.