Abstract

The processes which take place in this system may be described by a scheme which provides two possible paths for the degradation of electron excitation energy leading to a reduction in the quantum yield in the photoreacti0n product: 1) bimolecutar reaction of excited 2-naphthol (k 2) leading to deactivation of the excited molecules and competing with the formation of an excited hydrogen-bonded complex (induced nonradiative deactivation); and 2) degradation of the electron excitation of the molecule in the hydrogenbonded complex, competing with adiabatic proton transfer within the complex (k~).

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