Abstract

AbstractThe reaction of amino acids with functional groups in natural rubber has been studied by use of tritium labeled glycine as a tracer. The rate of reaction, in the latex phase, is found to be pH‐dependent with optimum rate at about pH 8. Reaction is considered to occur with rubber epoxide groups, since the level of incorporation of glycine correlates closely with the epoxide groups concentration. Competitive reactions with other amino acids and the effect of dimedone on glycine incorporation are also reported.

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