Non-negligibly negative role of e-waste-derived pyrogenic carbon in the soil washing of copper and polybrominated diphenyl ethers

Abstract

The open incineration of electrical and electronic waste (e-waste) results in the accumulation of pyrogenic carbon in the soil. However, the effect of the e-waste-derived pyrogenic carbon (E-PyC) on the performance of soil washing at e-waste incineration sites remains unclear. In this study, the effectiveness of a citrate-surfactant mixed solution in removing copper (Cu) and decabromodiphenyl ether (BDE209) at two e-waste incineration sites was evaluated. The removal efficiencies of Cu (24.6–51.3%) and BDE209 (13.0–27.9%) were low in both soils and were not significantly improved by ultrasonic. Soil organic matter analysis, hydrogen peroxide and thermal pretreatment experiments, and microscale soil particle characterization demonstrated that the poor removal of soil Cu and BDE209 was due to steric effects of E-PyC on the release of the solid fraction of pollutants and the competitive sorption of the labile fraction of pollutants by E-PyC. Weathering of soil Cu weakened the influence of E-PyC but strengthened the negative impact of natural organic matter (NOM) on soil Cu removal by promoting complexation between NOM and Cu2+ ions. This study demonstrates that the negative effect of E-PyC on Cu and BDE209 removal by soil washing is non-negligible, which has implications for decontaminating e-waste incineration sites by soil washing.