Abstract

The influence of B-site nonmagnetic substitution on the spiral spin ordering in multiferroic manganites is investigated by Monte Carlo simulation within the framework of classical Heisenberg model. It is revealed that the nonmagnetic substitution significantly suppressed the multiferroic phase transitions, consistent with experimental results. The boundary between ab-cycloidal phase and bc-cycloidal phase in the temperature-substitution phase diagram becomes faint gradually with increasing substitution level. A coexistence of two cycloidal spin phases is identified when the substitution level surpassed a threshold. The physical origin for the two-phase coexistence induced by the nonmagnetic B-site substitution is discussed.

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