Abstract
Thin films of linear low-density polyethylene show a significant time-dependent behavior, strongly reliant on temperature and strain rate effects. A constitutive nonlinear thermo-viscoelastic relation is developed to characterize the response of thin membranes up to yielding, in a wide range of temperatures, strain rates, and mechanical loading conditions. The presented plane stress orthotropic formulation involves the free volume theory of viscoelasticity and the time-temperature superposition principle, necessary to describe non-linearities and non-isothermal conditions. Uniaxial tension tests at constant strain rate and long-duration biaxial inflation experiments have been employed in the calibration of the material parameters. The model has been implemented in the Abaqus finite element code by means of a user-defined subroutine based on a recursive integration algorithm. The accuracy of the constitutive relation has been validated against experimental data of full field diaphragm inflation tests and uniaxial tension, relaxation and cyclic experiments, covering sub-ambient temperatures and strain rate ranges observed during the operation of stratospheric balloons.
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