Nonlinear Optical Response of Dispersed Medium Based on Conjugates Single-Walled Carbon Nanotubes with Phthalocyanines

Abstract

Nanosecond lasers have recently been widely involved in human activity. However, high-intensity laser radiation can cause severe damage to organs of vision and expensive photonic devices. Radiation in the near UV range is especially dangerous for human eyes, since it is strongly absorbed by biological media and is also invisible, i.e., the reaction time of the eye to such radiation is much lower than that of visible light. Passive limiters have high transmission (>70%) at a low light intensity and begin to “darken” only when the threshold value of the laser radiation intensity is reached. In this work, we studied liquid nanodispersed nonlinear optical limiters based on hybrids of single-walled carbon nanotubes (SWCNTs) with metal-free tetra(hydroxy)phthalocyanine (OH)4PcHH). The value of the hydrodynamic radius of separate particles after (OH)4PcHH binding increased from 288 ± 55 nm to 350 ± 60 nm, which confirms the attachment of phthalocyanine complexes to nanotubes. The third harmonic of a Nd:YAG nanosecond laser (355 nm, 20 ns) was used to study the nonlinear optical response. Based on a Z-scan with open-aperture and input-output dependence curves, third-order nonlinear optical absorption coefficients of 149, 236, and 229 cm/GW were obtained for dispersions of composites of SWCNTs and (OH)4PcHH in water, dimethylformamide (DMF), and dimethylsulfoxide (DMSO), respectively. Threshold values did not exceed 100 mJ/cm2. The Z-scan showed a gradual decrease in the duration of the laser pulse by 53%; however, near the focus, there was a sharp increase in the duration of the transmitted pulse, reaching a value of 29 ns in z = 0. This phenomenon confirms the occurrence of reverse saturable absorption in the investigated media and can be used in photonic devices to control the temporal characteristics of the signal. Thus, the possibility of protection of sensitive photonic devices and human eyes from nanosecond laser pulses in the near UV range by nanodispersed liquid media based on composites of SWCNTs with (OH)4PcHH has been discussed in this paper.