Abstract
One for all, all for one: A self-assembled M 4L 6 cage, incorporating small amounts of enantiopure subcomponents at the peripheries, forms predominantly with a one-handed twist at all metal centers. Strong stereochemical coupling between metal centers in the cage amplifies energy differences between the and diastereomers as compared to analogous mononuclear metal complexes (see picture; red and gray bars denote chiral and achiral subcomponents, respectively).
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