Abstract
Abstract Spontaneous chemical oscillations are uncovered in the uncatalyzed bromate–pyrocatechol reaction conducted in a stirred batch reactor. Phase diagrams show that the oscillatory behavior is more sensitive to the ratio of [bromate]/[pyrocatechol] than their actual concentrations. The long induction time observed in the system is insensitive to the initial presence of brominated pyrocatechol species. Quenching experiments illustrate that the studied chemical oscillator is both bromide and radical controlled. In addition, this new uncatalyzed bromate oscillator exhibits both light-induced and light-quenched oscillatory behaviors. Preliminary mechanistic characterization with UV/vis absorption method and mass spectrometry suggests the formation of bromo-1,2-benzoquinone through the reaction between pyrocatechol and bromine.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
