Nonlinear dynamical modeling of adsorption and desorption processes with power-law kinetics: Application to CO_{2} capture.

Abstract

Modeling of random sequential adsorption (RSA) process is studied in this paper as this kind of process is close to the surface adsorption phenomenon that is, for instance, exploited in gas sensors or for liquid or gas purification. Analysis and simulation of the RSA process is first performed to highlight a power-law kinetic behavior. Such behaviors are often modeled in the literature with fractional models. The paper, however, shows that fractional models are not able to capture some important properties of the RSA process. A nonlinear model and the associated parameters tuning method are, thus, proposed. A discussion on the ability of the proposed model to capture the power-law kinetics without exhibiting some of the drawbacks of fractional models is proposed. This nonlinear model is then modified to take into account the reverse desorption process. The proposed modeling approach is applied to experimental data of CO_{2} capture.